直接熔样正热电离质谱法测定二硼化锆中硼同位素丰度

本工作选择m/z88(23 Na210BO2+)和m/z89(23 Na211BO2+)的Na2BO2+作为检测离子,研究了同位素干扰、涂样技术、ZrB2样品处理等对硼同位素测定的影响,建立了快速准确测定ZrB2中硼同位素丰度的正热电离质谱法。实验复现了硼同位素标准物质的标准值,对酸溶法分解试样后涂样和直接熔融法涂样测量结果的精密度进行了比较。结果表明,采用直接熔融法涂样可以快速准确地测定ZrB2中硼同位素丰度,δ10B同位素丰度测定结果精密度优于0.020%。     

直纺亮光抗倒伏波浪扁平涤纶FDY的开发

探讨了直纺83 dtex/114 f波浪扁平涤纶全拉伸丝(FDY)的工艺制备过程。试验证明,在熔体输送温度276~282℃,纺丝温度286~290℃,喷丝板规格DIO φ104 mm-114孔、"王"字形,环吹风压10~15 Pa,含油率1.1%~1.2%,卷绕速度3 800~4 200 m/min的工艺参数下纺制83 dtex/114 f波浪扁平涤纶FDY时,生产稳定,满卷率高,外观情况良好,袜带均匀亮丽,可批量生产。此新产品可用于制作高档布艺沙发表层面料,具有抗倒伏、色彩艳丽等功效。     

Investigation of flame characteristics using various design parameters in a pulverized coal burner for oxy‐fuel retrofitting

In oxy‐coal combustion for carbon capture and storage, oxygen and recirculated CO₂ are used as oxidizers instead of air to produce CO₂‐rich flue gas. Owing to differences between the physical and chemical properties of CO₂ and N₂, the development of a burner and boiler system based on fundamental understanding of the flame type, heat transfer, and NOx emission is required. In this study, computational fluid dynamic analysis incorporating comprehensive coal conversion models was performed to investigate the combustion characteristics of a 30 MWth tangential vane swirl pulverized coal burner. Various burner design parameters were evaluated, including the influence of the burner geometry on the swirl strength, direct O₂ injection, and O₂ concentrations in the primary and secondary oxidizers. The flame characteristics were sensitive to the oxygen concentration in the primary oxidizer. The performance of direct O₂ injection around the primary oxidizer with low O₂ concentration was dependent on the mixing of the fuel and oxidizer. The predictions showed that swirl number adjustment and careful direct oxygen injection design are essential for retrofitting air‐firing pulverized coal burners as oxy‐firing burners.     

我国矿业海外直接投资区位分布与空间经济效应研究——以世界主要经济体为例

以我国矿业对世界主要经济体直接投资为例, 基于2009~2018年投资存量数据, 在多区域结构分析框架下, 运用投资多样性指数、动态时空模型、灰色系统预测模型分别对投资区位分布特征、空间经济效应以及未来分布趋势进行了研究。结果显示: ① 2009~2018年, 我国矿业对世界主要经济体直接投资区位分布呈现出“由高度集中转向渐进扩散”“高者仍高、低者仍低”的集团俱乐部式时空分布特征;② 投资区位分布受到了来自于其他国家(地区)全局效应和相邻效应的影响;③ 2019~2020年, 在空间经济效应作用下, 投资渐进扩散趋势仍将持续, 集团俱乐部式分布有所减弱;我国矿业对欧盟、俄罗斯联邦、东盟、美国的投资机会及热度将有所增加。依据研究结果, 提出了我国矿业海外直接投资的启示及建议。     

Preparation and characterization of polyvinylchloride membrane embedded with Cu nanoparticles for electrochemical oxidation in direct methanol fuel cell

Copper nanoparticles were prepared by the chemical reduction method. These copper particles were embedded into the polyvinylchloride (PVC) matrix as support and used as an electrode (PVC/Cu) for the oxidation of methanol fuel for improving the current response. The PVC/Cu electrodes were characterized by thermal gravimetric analysis (TGA) for thermal stability of the electrode, X-ray diffraction (XRD) for identification of copper nanoparticles in the electrode, Fourier transform infrared spectroscopy (FTIR) to identify the interaction between PVC and Cu and scan electron microscopy (SEM) with EDAX for the morphology of the electrode. The electrocatalytic activity of the electrode was characterized by the cyclic voltammetry, linear sweep voltammetry, and chronoamperometry techniques. An increase in the electrode activity was observed with the increase of copper quantity from 0.18 g (PVC/Cu-0.18 g) to 0.24 g (PVC/Cu-0.24 g) and the maximum was found at 0.24 g of copper in the electrode. Also, it was observed that the electrode achieved the maximum catalytic current in 0.5 mol/L CH₃OH + 1 mol/L NaOH solution. FTIR identified that water molecules, C—H group, copper nanoparticle and its oxide were available in the electrode. SEM images with EDAX showed that copper particles were properly embedded in the polyvinylchloride matrix.     

Methanol and proton transport through chitosan-phosphotungstic acid membranes for direct methanol fuel cell

Composite chitosan-phosphotungstic acid membranes were synthesized by ionotropic gelation. Their liquid uptake is higher for thin membranes (23 ± 2 μm), while it is lower (~70%) for thicker membranes (50-70 μm). Polarization curves recorded using single module fuel cell at 70°C allowed to estimate a peak power density of 60 mW cm⁻² by using 1 M as methanol and low Pt and Pt/Ru loadings (0.5 and 3 mg cm⁻²) at the cathode and at the anode, respectively. Electrochemical impedance spectroscopy was used to estimate the membrane conductivity and to model the electrochemical behavior of methanol electrooxidation inside the fuel cell revealing a two-step mechanism mainly responsible of overall kinetic losses. Transport of methanol inside the membrane was studied by potentiostatic measurements, allowing to estimate a methanol diffusivity of 3.6 × 10⁻⁶ cm² s⁻¹.     

汽油缸内直喷喷雾在不同壁温和二次喷射下的附壁油膜特性研究

采用激光诱导荧光(laser induced fluorescence,LIF)法测量缸内直喷喷油器喷雾附壁油膜的厚度分布,研究了附壁油膜质量和平均厚度随不同的壁面温度和喷射策略的变化。结果表明:常温壁面下油膜呈"波浪状",热壁面下油膜的边缘轮廓呈"带状"凸起,在壁面温度为413K时,还出现了聚集的小液滴。保持总喷油量不变,随着壁面温度的增大,单次喷射的附壁油膜质量逐渐减小,二次喷射的附壁油膜质量先减小后增大,单/二次喷射的附壁油膜平均厚度都逐渐增大;相对于单次喷射,相同热壁面温度下的二次喷射附壁油膜平均厚度都较小,在壁面温度同为413K时最多减小了42%。仅增加第二次喷射的喷油脉宽,壁面温度为298K和373K时的附壁油膜质量先增大后减小,壁面温度为413K时附壁油膜质量逐渐增大;相同喷油脉宽下,壁面温度为413K时附壁油膜平均厚度最大,而壁面温度为298K和373K时附壁油膜平均厚度与喷油间隔相关。     

Visualization of hydrogen jet evolution and combustion under simulated direct-injection compression-ignition engine conditions

The evolution and combustion of H₂ jets were investigated in an optically-accessible constant-volume chamber under simulated direct-injection (DI) compression-ignition (CI) engine conditions. The parameters varied include injection pressure (84–140 bar) and ambient temperature (1000–1140 K). A detailed characterization of the injector system and the ensuing jet penetration process is reported first. High-speed schlieren imaging, OH1 chemiluminescence imaging and pressure trace measurements were subsequently used to investigate the auto-ignition and combustion of the H₂ jets. The results show that the ignition delay of H₂ jets under such conditions is sensitive to ambient temperature variations, but not to injection pressure. Optical imaging reveals that the combustion of H₂ jets mostly initiated from a localized kernel, before spreading to engulf the whole jet volume downstream of ignition location. The imaging also indicates that after ignition, the flame recesses back towards the nozzle and appears to attach to the nozzle to form a diffusion flame structure.     

Prediction of hot tearing susceptibility of direct chill casting of AA6111 alloys via finite element simulations

To predict hot tearing susceptibility (HTS) during solidification and improve the quality of Al alloy castings, constitutive equations for AA6111 alloys were developed using a direct finite element (FE) method. A hot tearing model was established for direct chill (DC) casting of industrial AA6111 alloys via coupling FE model and hot tearing criterion. By applying this model to real manufacture processes, the effects of casting speed, bottom cooling, secondary cooling, and geometric variations on the HTS were revealed. The results show that the HTS of the billet increases as the speed and billet radius increase, while it reduces as the interfacial heat transfer coefficient at the bottom or secondary water-cooling rate increases. This model shows the capabilities of incorporating maximum pore fraction in simulating hot tearing initiation, which will have a significant impact on optimizing casting conditions and chemistry for minimizing HTS and thus controlling the casting quality.     

Effects of heat treatment on microstructure and mechanical properties of Inconel 625 alloy fabricated by wire arc additive manufacturing process

The microstructure and mechanical properties of Inconel 625 alloy fabricated by wire arc additive manufacturing process were evaluated under as-prepared and heat-treated conditions. A dendritic Ni-based solid solution phase along with (Nb, Ti)C carbide, Laves, and δ-Ni₃Nb secondary phases were developed in the microstructure of the as-prepared alloy. Solution heat treatment led to the dissolution of Laves and Ni₃Nb phases. In addition, dendrites were replaced with large columnar grains. Aging heat treatment resulted in the formation of grain boundary M₂₃C₆ carbide and nanometric γ″ precipitates. Hardness, yield and tensile strengths, as well as elongation of the as-prepared part, were close to those of the cast alloy and its fracture occurred in a transgranular ductile mode. Solution heat treatment improved hardness and yield strength and declined the elongation, but it did not have a considerable impact on the tensile strength. Furthermore, aging heat treatment caused the tensile properties to deteriorate and changed the fracture to a mixture of transgranular ductile and intergranular brittle mode.